Free radical chain reactions in organic synthesis

Main Author: Motherwell, William B.,
Other Authors: Crich, David,, ScienceDirect (Online service)
Format: eBook
Language: English
Published: London ; San Diego, California : Academic Press, 1992.
Physical Description: 1 online resource (289 pages) : illustrations.
Series: Best synthetic methods.
Subjects:
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100 1 |a Motherwell, William B.,  |e author. 
245 1 0 |a Free radical chain reactions in organic synthesis /  |c William B. Motherwell and David Crich. 
264 1 |a London ;  |a San Diego, California :  |b Academic Press,  |c 1992. 
264 4 |c ©1992. 
300 |a 1 online resource (289 pages) :  |b illustrations. 
336 |a text  |b txt  |2 rdacontent. 
337 |a computer  |b c  |2 rdamedia. 
338 |a online resource  |b cr  |2 rdacarrier. 
490 1 |a Best Synthetic Methods. 
504 |a Includes bibliographical references at the end of each chapters and index. 
588 0 |a Online resource; title from PDF title page (ebrary, viewed November 12, 2014). 
505 0 |a ""Front Cover ""; ""Free Radical Chain Reactions in Organic Synthesis""; ""Copyright Page ""; ""Table of Contents ""; ""Dedication ""; ""Foreword""; ""Preface""; ""Detailed Contents""; ""Chapter 1. Some basic concepts of free radical chain reactions""; ""1.1 Introduction""; ""1.2 The advantages""; ""1.3 The relative ""character"" of various radical species""; ""1.4 Determinant factors in the production of a successful free radical chain reaction""; ""1.5 The initiation ceremony""; ""1.6 Strategy and design in synthetic sequences involving carbon centred radical reactions"" 
505 8 |a ""1.7 Some practical guidelines""""1.8 Overview and perspectives""; ""References""; ""Chapter 2. Books and review articles""; ""2.1 Some earlier basic texts and reviews (pre-1980)""; ""2.2 General books and reviews (post-1980)""; ""2.3 Recent books and articles dealing with more specific aspects of free radical reactions""; ""Chapter 3. Substitution reactions""; ""3.1 Dehalogenation (RX â?? RH, X = halogen)""; ""3.2 Deoxygenation reactions (ROH â?? RH)""; ""3.3 Deamination reactions (RNH2 â?? RH)""; ""3.4 Denitration reactions (RNO2 â?? RH)"" 
505 8 |a ""3.5 Reductive homolytic cleavage of the carbonâ€?sulphur bond""""3.6 Deselenation reactions""; ""3.7 Decarboxylation reactions""; ""3.8 Functional group interchange using organometallic derivatives of boron, mercury and cobalt""; ""References""; ""Chapter 4. Olefin forming β-elimination reactions""; ""4.1 Introduction""; ""4.2 Alkenes from vicinal dihalides""; ""4.3 Alkenes from vicinal diols via 1,2-bis-xanthate esters""; ""4.4 Alkene formation by stannane induced fragmentation of thiocarbonyl-O-ester derivatives of β-hydroxy sulphides, sulphones and isocyanides"" 
505 8 |a ""4.5 Olefin formation from β-halogeno sulphides, sulphoxides, sulphones and selenides""""4.6 Alkenes from vicinally functionalized nitro derivatives""; ""References""; ""Chapter 5. Preparative free radical rearrangement reactions""; ""5.1 Introduction""; ""5.2 Acetoxyl group migration reactions""; ""5.3 Radical rearrangements involving allylic systems""; ""5.4 The cyclopropylcarbinylâ€?homoallylic radical rearrangement""; ""5.5 Homobenzylic rearrangements""; ""5.6 Determinental factors in some miscellaneous radical induced carbocyclic ring cleavage reactions"" 
505 8 |a ""5.7 Ring opening reactions of epoxides by a neighbouring carbon centred radical""""References""; ""Chapter 6. Intermolecular carbonâ€?carbon bond forming free radical chain reactions""; ""6.1 Addition of carbon centred radicals to multiple bonds""; ""6.2 Stereochemical aspects""; ""6.3 Addition to alkenes with chain transfer by hydrogen atom abstraction""; ""6.4 Addition to alkenes with chain transfer by formation of a carbonâ€?heteroatom bond""; ""6.5 Addition to alkenes with concomitant displacement of a chain carrying radical""; ""6.6 Addition to alkynes"" 
650 0 |a Organic compounds  |x Synthesis. 
650 0 |a Free radical reactions. 
650 7 |a SCIENCE  |x Chemistry  |x Organic.  |2 bisacsh. 
650 7 |a Free radical reactions.  |2 fast. 
650 7 |a Organic compounds  |x Synthesis.  |2 fast. 
655 4 |a Electronic books. 
700 1 |a Crich, David,  |e author. 
710 2 |a ScienceDirect (Online service) 
776 0 8 |i Print version:  |a Motherwell, William B.  |t Free radical chain reactions in organic synthesis.  |d London ; San Diego, California : Academic Press, ©1992  |h xix, 268 pages  |k Best synthetic methods.  |z 9780125087605. 
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