Tin in organic synthesis
Tin in Organic Synthesis is a systematic presentation of the organic chemistry of tin. This book discusses the significant advances that have been made with regard to the applications of organotin compounds as reagents or intermediates in organic synthesis and points out directions for future develo...
| Main Author: | Pereyre, Michel. |
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| Other Authors: | Quintard, Jean-Paul., Rahm, Alain., ScienceDirect (Online service) |
| Format: | eBook |
| Language: | English |
| Published: |
London ; Boston :
Butterworths,
1987.
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| Physical Description: |
1 online resource (342 pages) |
| Subjects: |
| Summary: |
Tin in Organic Synthesis is a systematic presentation of the organic chemistry of tin. This book discusses the significant advances that have been made with regard to the applications of organotin compounds as reagents or intermediates in organic synthesis and points out directions for future developments. This monograph is comprised of 17 chapters divided into four sections. Following a brief introduction to organotin chemistry, the production of the organotin reagents, which are most usually employed in organic synthesis, is described. Special emphasis is placed on the creation of a fresh ti. |
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| Item Description: |
Includes bibliographical references and index. Use copy Restrictions unspecified star MiAaHDL. Electronic reproduction. [S.l.] : HathiTrust Digital Library, 2011. MiAaHDL. Master and use copy. Digital master created according to Benchmark for Faithful Digital Reproductions of Monographs and Serials, Version 1. Digital Library Federation, December 2002. http://purl.oclc.org/DLF/benchrepro0212 MiAaHDL. Front Cover; Tin in Organic Synthesis; Copyright Page; Foreword; Preface; Table of Contents; Abbreviations; Part One: Introduction to organotin chemistry; Chapter 1. General organotin chemistry; 1.1 Nomenclature; 1.2 Literature; 1.3 Tin and its bonds; 1.4 Some physical data; 1.5 Toxicity and hazards; Chapter 2. Preparation of organotin reagents; 2.1 Synthesis of basic organotin reagents; 2.2 Creation of a fresh tin-carbon bond; 2.3 Functional transformations of groups bound to tin; References; Part Two: Synthetic Applications Involving Tin-Hydrogen Bonds. Chapter 3. Reduction of organic halides3.1 General; 3.2 Reduction of simple organic halides and polyhalides; 3.3 Chemoselective reduction of polyfunctional halides; 3.4 Stereochemistry; 3.5 Reductions with free-radical rearrangements or fragmentations; Chapter 4. Reduction of carbonyl compounds; 4.1 Aldehydes and ketones; 4.2 Acyl halides; 4.3 Esters and related compounds; Chapter 5. Reduction of thio, seleno and telluro compounds; 5.1 Thio derivatives; 5.2 Seleno derivatives; 5.3 Telluro derivatives; Chapter 6. Reduction of nitrogen compounds. 6.1 Isocyanides, isocyanates and related compounds6.2 Nitro compounds; 6.3 Miscellaneous reactions; Chapter 7. Reduction of unsaturated carbon-carbon bonds; 7.1 ÜÝ-Unsaturated ketones and aldehydes; 7.2 ÜÝ-Unsaturated nitriles and esters; 7.3 Functionalization via mercuric compounds; References; Part Three: Synthetic applications involving tin-carbon bonds; Chapter 8. Access to carbon-hydrogen and carbon-heteroatom bonds; 8.1 Carbon-hydrogen bonds; 8.2 Carbon-halogen bonds; 8.3 Carbon-oxygen bonds; related oxidation reactions; 8.4 Other carbon-heteroatom bonds. Chapter 9. Transmetallation and metallation of organotin compounds9.1 General features of transmetallation and metallation reactions; 9.2 Transmetallation of vinyl organotin compounds; 9.3 Transmetallation of Ü-heterosubstituted organotin compounds; 9.4 Transmetallation of benzyl- and allyltin compounds; 9.5 Transmetallation of miscellaneous organotin compounds; 9.6 Metallation of organotin compounds; Chapter 10. Access to carbon-carbon bonds; 10.1 Via substitution reactions; 10.2 Via addition reactions; 10.3 Via elimination reactions; References. Part Four: Synthetic applications involving tin-heteroatom bondsChapter 11. Organotin alkoxides; 11.1 In substitution reactions; 11.2 In oxidation reactions; 11.3 In addition reactions; 11.4 As catalysts; Chapter 12. Organotin enolates; 12.1 Organotin(IV) enolates; 12.2 Tin(II) enolates; Chapter 13. Organotin oxides and peroxides; 13.1 Oxides; 13.2 Peroxides; Chapter 14. Organotin esters; 14.1 Carboxylates; 14.2 Other esters; Chapter 15. Organotin compounds with tin-nitrogen bonds; 15.1 Simple amines; 15.2 Other compounds with Sn-N bonds; Chapter 16. Organotin compounds with tin-sulphur bonds. Tin in Organic Synthesis is a systematic presentation of the organic chemistry of tin. This book discusses the significant advances that have been made with regard to the applications of organotin compounds as reagents or intermediates in organic synthesis and points out directions for future developments. This monograph is comprised of 17 chapters divided into four sections. Following a brief introduction to organotin chemistry, the production of the organotin reagents, which are most usually employed in organic synthesis, is described. Special emphasis is placed on the creation of a fresh ti. English. |
| Physical Description: |
1 online resource (342 pages) |
| Format: |
Master and use copy. Digital master created according to Benchmark for Faithful Digital Reproductions of Monographs and Serials, Version 1. Digital Library Federation, December 2002. |
| Bibliography: |
Includes bibliographical references and index. |
| ISBN: |
9781483161075 1483161072 |