Analytical methods
| Other Authors: | Morrison, James D., 1936-, ScienceDirect (Online service) |
|---|---|
| Format: | eBook |
| Language: | English |
| Published: |
New York :
Academic Press,
[1983]
|
| Physical Description: |
1 online resource. |
| Series: |
Asymmetric synthesis ;
v. 1. |
| Subjects: |
Table of Contents:
- Front Cover; Asymmetric Synthesis; Copyright Page; Dedication; Table of Contents; Contributors; Preface; Chapter 1. A Summary of Ways to Obtain Optically Active Compounds; I. Introduction; II. Obtaining Chiral Compounds by the FRN Method; III. Isolating Chiral Compounds from Natural Sources; IV. Resolution of Racemic Modifications by the Physical Separation of Intermediate Diastereomers; V. Asymmetric Transformations; VI. Kinetic Resolution; VII. Asymmetric Synthesis; References; Chapter 2. Polarimetry; I. Introduction; II. Instrumentation; III. Advantages of Optical Rotation Measurements.
- IV. Requirements for Precision of DataReferences; Chapter 3. Competitive Reaction Methods for the Determination of Maximum Specific Rotations; I. Introduction; II. Principles of Kinetic Resolution; III. Calculation of the Specific Rotation of an Enantiomer by Means of a Method Using Asymmetric Destruction of the Corresponding Racemic Mixture; IV. Calculation of the Specific Rotation of an Enantiomer by Means of a Method Using Two Reciprocal Kinetic Resolutions; V. Conclusion; References; Chapter 4. Isotope-Dilution Techniques; I. Introduction; II. History; III. Theory; IV. Errors; V. Examples.
- Chapter 7. Nuclear Magnetic Resonance Analysis Using Chiral DerivativesI. Introduction; II. Application of Chemical Shift Nonequivalence; III. Application of Induced Chemical Shift Nonequivalence; References; Chapter 8. Nuclear Magnetic Resonance Analysis Using Chiral Solvating Agents; I. Introduction; II. Principles; III. Chiral Solvating Agents, Solutes, and Association Interactions; IV. Practical Experimental Considerations; V. Comparison with the Chiral Lanthanide Shift Reagent Method; VI. Conclusions; References; Chapter 9. Nuclear Magnetic Resonance Analysis Using Chiral Shift Reagents.
- I. IntroductionII. General Features of Shift Reagents; III. Structural Isomerism in Chiral Shift Reagents; IV. Variations in Structure; V. Mechanism of Action; VI. Uses of Chiral Shift Reagents; VII. Experimental Procedures; References; Index.