Copper(I)-catalyzed stereoselective borylation reactions multisubstituted alkenyl and allylic boronates /

This book focuses on the development of novel functionalized organoboron compounds and those synthetic methods. High degrees of chemo-, regio-, and stereoselectivities of the borylation reactions are attained through catalyst design and optimization. Furthermore, the selectivity-determining mechanis...

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Main Author: Ozawa, Yu,
Other Authors: SpringerLink (Online service)
Format: eBook
Language: English
Published: Singapore : Springer, [2023]
Physical Description: 1 online resource (xiii, 226 pages) : illustrations (some color).
Series: Springer theses.
Subjects:
Table of Contents:
  • 1. General Introduction
  • 2. Modification of QuinoxP*-Type Bisphosphine Ligands for High-Performance Asymmetric Boryl Substitution of Racemic Allyl Electrophiles
  • 3. Allylcopper(I) Isomerization-Enabled Copper(I)-Catalyzed Intramolecular Alkylboration of Terminal Allenes
  • 4. Intermolecular Alkylboration of gem-Disubstituted Allenes for Stereoselective Synthesis of Multi-Alkylated Allylic Boronates
  • 5. Computational Investigation on Copper(I)-Catalyzed Enantioselective Radical Borylation of Benzyl Halides
  • 6. Summary of This Thesis.