Organic nanoreactors from molecular to supramolecular organic compounds /
Organic Nanoreactors: From Molecular to Supramolecular Organic Compounds provides a unique overview of synthetic, porous organic compounds containing a cavity which can encapsulate one or more guest(s). Confined space within a nanoreactor can isolate the guest(s) from the bulk and effectively influe...
| Other Authors: | Sadjadi, Samahe,, ScienceDirect (Online service) |
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| Format: | eBook |
| Language: | English |
| Published: |
London :
Academic Press, an imprint of Elsevier,
[2016]
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| Physical Description: |
1 online resource : illustrations. |
| Subjects: |
| Summary: |
Organic Nanoreactors: From Molecular to Supramolecular Organic Compounds provides a unique overview of synthetic, porous organic compounds containing a cavity which can encapsulate one or more guest(s). Confined space within a nanoreactor can isolate the guest(s) from the bulk and effectively influence the reaction inside the nanoreactor. Naturally occurring enzymes are compelling catalysts for selective reactions as their three-dimensional structures build up clefts, caves, or niches in which the active site is located. Additionally, reactive sites carrying special functional groups allow only specific reagents to react in a particular way, to lead to specific enantiomers as products. Equipped with suitable functional groups, then, nanoreactors form a new class of biomimetic compounds, which have multiple important applications in the synthesis of nanomaterials, catalysis, enzyme immobilization, enzyme therapy, and more. This book addresses various synthetic, organic nanoreactors, updating the previous decade of research and examining recent advances in the topic for the first comprehensive overview of this exciting group of compounds, and their practical applications. Bringing in the Editor's experience in both academic research and industrial applications, Organic Nanoreactors focuses on the properties and applications of well-known as well as little-examined nanoreactor compounds and materials and includes brief overviews of synthetic routes and characterization methods. |
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| Item Description: |
Includes bibliographical references and index. Organic Nanoreactors: From Molecular to Supramolecular Organic Compounds provides a unique overview of synthetic, porous organic compounds containing a cavity which can encapsulate one or more guest(s). Confined space within a nanoreactor can isolate the guest(s) from the bulk and effectively influence the reaction inside the nanoreactor. Naturally occurring enzymes are compelling catalysts for selective reactions as their three-dimensional structures build up clefts, caves, or niches in which the active site is located. Additionally, reactive sites carrying special functional groups allow only specific reagents to react in a particular way, to lead to specific enantiomers as products. Equipped with suitable functional groups, then, nanoreactors form a new class of biomimetic compounds, which have multiple important applications in the synthesis of nanomaterials, catalysis, enzyme immobilization, enzyme therapy, and more. This book addresses various synthetic, organic nanoreactors, updating the previous decade of research and examining recent advances in the topic for the first comprehensive overview of this exciting group of compounds, and their practical applications. Bringing in the Editor's experience in both academic research and industrial applications, Organic Nanoreactors focuses on the properties and applications of well-known as well as little-examined nanoreactor compounds and materials and includes brief overviews of synthetic routes and characterization methods. Cover -- Title Page -- Copyright Page -- Contents -- List of Contributors -- Chapter 1 -- Introduction to Nanoreactors -- 1 -- Approaches to artificial enzymes -- 2 -- Nanoreactors -- 2.1 -- Nanoreactor Definition -- 2.2 -- Encapsulation Effects -- 2.3 -- Reaction Kinetics Inside Nanoreactors -- 2.4 -- Product Inhibition -- 2.5 -- Nanoreactor Classification -- 2.5.1 -- Natural or Synthetic Nanoreactors -- 2.5.2 -- Biological Nanoreactors -- 2.5.3 -- Self-Assembled Nanoreactors -- 3 -- Nanoreactor potential applications -- 3.1 -- Catalysis -- 3.2 -- Protection and Stabilization. 3.3 -- Templating and Stabilizing of Nanomaterials -- 3.4 -- Polymer Science -- 3.5 -- Development of Nanomedicines -- 3.6 -- Sensors -- 4 -- Conclusions -- References -- Chapter 2 -- Cyclodextrins as Porous Material for Catalysis -- 1 -- Cyclodextrins: a brief overview -- 1.1 -- Structure and Supramolecular Properties -- 1.2 -- CD-Based Polymers -- 1.2.1 -- Cross-Linked CD-Based Polymers -- 1.2.2 -- Linear CD-Based Polymers -- 1.3 -- Applications of CDs -- 2 -- CD-based polymers as mass-transfer promoters -- 2.1 -- Ester Hydrolysis -- 2.2 -- Nucleophilic Substitution -- 2.3 -- Oxidation. 2.4 -- Aldol Condensation -- 2.5 -- Organometallic Catalysis -- 3 -- Imprinted CD-based polymers for catalysis -- 3.1 -- Wacker Oxidation -- 3.2 -- Oxidative Coupling -- 3.2.1 -- Naphthol Derivatives Homocoupling -- 4 -- CD-based nanosponges -- 5 -- Conclusions -- References -- Chapter 3 -- The Use of Cucurbit[n]urils as Organic Nanoreactors -- 1 -- Introduction -- 2 -- Physical properties of cucurbit[n]urils -- 3 -- Host properties of cucurbit[n]urils -- 3.1 -- Cationic Guests -- 3.2 -- Neutral Guests -- 3.3 -- Other Guests -- 4 -- Effects of cucurbit[n]uril hosts on guest physical and structural properties. 4.1 -- Effects of CB[n] Hosts on Guest Solubility -- 4.2 -- Effects of CB[n] Hosts on Guest Spectroscopic Properties -- 4.3 -- Effects of CB[n] Hosts on Guest Structure and Isomerization -- 4.4 -- Effects of CB[n] Hosts on Guest Aggregation -- 5 -- Effects of Cucurbit[n]urils on guest reactivity and chemical properties -- 5.1 -- CB[n] Nanoreactor Control of Guest Acidity -- 5.2 -- CB[n] Nanoreactor Control of Guest Electrochemical Properties -- 5.3 -- CB[n] Nanoreactors for Enhanced Reactant Solubility and Stability -- 5.4 -- CB[n] Nanoreactors for Reactant Geometry and Stereochemistry Control. 5.5 -- CB[n] Nanoreactors for Reaction Templating -- 5.6 -- CB[n] Nanoreactors for Reaction Catalysis -- 6 -- Conclusions -- References -- Chapter 4 -- Systems Based on Calixarenes as the Basis for the Creation of Catalysts and Nanocontainers -- 1 -- Introduction -- 2 -- Synthesis and structure of calixarenes -- 2.1 -- Calixarenes and Thiacalixarenes -- 2.2 -- Calix[4]resorcinarenes and Pyrogallolarenes -- 3 -- Macromolecular catalysts based on macrocyclic receptors -- 4 -- Supramolecular catalysis by calixarenes -- 5 -- Supramolecular catalysis by metal complexes based on calixarenes. 6 -- Supramolecular systems for controlled binding/isolation of organic molecules and biosubstrates. |
| Physical Description: |
1 online resource : illustrations. |
| Bibliography: |
Includes bibliographical references and index. |
| ISBN: |
9780128018101 0128018100 |