Copper-catalyzed multi-component reactions synthesis of nitrogen-containing polycyclic compounds /
A copper-catalyzed direct synthesis of 2-(aminomethyl)indoles by catalytic domino reaction including multi-component coupling was developed, and is the first example of a three-component indole formation without producing salts as a byproduct. Based on this reaction, a copper-catalyzed synthesis of...
| Main Author: | Ohta, Yusuke. |
|---|---|
| Other Authors: | SpringerLink (Online service) |
| Format: | eBook |
| Language: | English |
| Published: |
Berlin ; Heidelberg ; New York :
Springer,
©2011.
Berlin ; Heidelberg ; New York : [2011] |
| Physical Description: |
1 online resource (xv, 102 pages). |
| Series: |
Springer theses.
|
| Subjects: |
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| 100 | 1 | |a Ohta, Yusuke. | |
| 245 | 1 | 0 | |a Copper-catalyzed multi-component reactions : |b synthesis of nitrogen-containing polycyclic compounds / |c Yusuke Ohta. |
| 260 | |a Berlin ; |a Heidelberg ; |a New York : |b Springer, |c ©2011. | ||
| 264 | 1 | |a Berlin ; |a Heidelberg ; |a New York : |b Springer, |c [2011] | |
| 264 | 4 | |c ©2011. | |
| 300 | |a 1 online resource (xv, 102 pages). | ||
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| 490 | 1 | |a Springer theses. | |
| 502 | |b Ph. D. |c Kyoto University |d 2010. | ||
| 504 | |a Includes bibliographical references. | ||
| 520 | |a A copper-catalyzed direct synthesis of 2-(aminomethyl)indoles by catalytic domino reaction including multi-component coupling was developed, and is the first example of a three-component indole formation without producing salts as a byproduct. Based on this reaction, a copper-catalyzed synthesis of 3-(aminomethyl)isoquinoline was accomplished which represents an unprecedented isoquinoline synthesis through a four-component coupling reaction. Following these results, extensive application studies using one-pot palladium-, acid-, or base-promoted cyclization revealed that indole- or isoquinoline. | ||
| 588 | 0 | |a Print version record. | |
| 505 | 0 | |a Copper-Catalyzed Multi-Component Reactions; Supervisor's Foreword; Acknowledgments; Contents; 1 Introduction; References; Part I Synthesis of Indole Derivatives; 2 Construction of 2-(Aminomethyl)indoles Through Copper-Catalyzed Domino Three-Component Coupling and Cyclization; 3 Facile Synthesis of 1,2,3,4-Tetrahydro- beta -Carbolines by One-Pot Domino Three-Component Indole Formation and Nucleophilic Cyclization; 4 Concise Synthesis of Indole-Fused 1,4-Diazepines through Copper(I)-Catalyzed Domino Three-Component Coupling-Cyclization-N-Arylation under Microwave Irradiation. | |
| 505 | 8 | |a Part II Synthesis of Isoquinoline Derivatives5 Facile Synthesis of 3-(Aminomethyl)isoquinoline by Copper-Catalyzed Domino Four-Component Coupling and Cyclization; 6 Rapid Access to 3-(Aminomethyl)isoquinoline-Fused Polycyclic Compounds by Copper-Catalyzed Four Component Coupling, Cascade Cyclization, and Oxidation; 7 Conclusions. | |
| 506 | |a University staff and students only. Requires University Computer Account login off-campus. | ||
| 650 | 0 | |a Polycyclic compounds |x Synthesis. | |
| 650 | 6 | |a Composés polycycliques |x Synthèse. | |
| 650 | 7 | |a SCIENCE |x Chemistry |x Organic. |2 bisacsh. | |
| 650 | 7 | |a Chimie. |2 eclas. | |
| 650 | 7 | |a Science des matériaux. |2 eclas. | |
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| 655 | 2 | |a Academic Dissertation. | |
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| 655 | 7 | |a Thèses et écrits académiques. |2 rvmgf. | |
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